The Beginnings of Synthetic Organic Chemistry: Zinc Alkyls and the Kazan’ School
نویسنده
چکیده
It is scant exaggeration to say that modern organic synthesis would be almost inconceivable without the important carbon-carbon bond-forming reactions involving the addition or organometallic reagents to aldehydes, ketones and acid derivatives. Today, the addition reactions of organometallic reagents of most elements of the periodic table have been explored in great detail, permitting the synthetic organic chemist to exploit the unique reactivity of the alkyl derivatives of many elements of the periodic table to obtain that degree of control that gives modern organic synthesis much of its power.
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Organometallic chemistry. Past, present, and future*
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